Roberto Rinaldi

Reader in Applied Chemistry at Imperial College London

Schools

  • Imperial College London

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Biography

Imperial College London

Born in 1979 in Brazil, Roberto Rinaldi is a naturalised British scientist and a Reader / Associate Professor in Applied Chemistry. His commitment to Sustainable Chemistry for the Circular Economy has steered his research primarily towards heterogeneous catalysis. More specifically, Rinaldi has centred his research on using plant biomass, such as inedible parts like lignin and cellulose, as renewable raw materials for chemical and biofuel production. His recent work has expanded to include the chemical recycling of plastics and composites, further reinforcing the sustainability of the chemical industry.

Rinaldi's academic journey began at the University of Campinas (UNICAMP), where in 2006, he successfully defended his PhD thesis on the epoxidation of nucleophilic olefins using aluminium oxide and hydrogen peroxide, under the supervision of Prof. Ulf Schuchardt. The subsequent year marked his move to Germany, where he joined the renowned Max-Planck-Institut (MPI) für Kohlenforschung as a postdoctoral research fellow in Prof. Ferdi Schüth's group. During his early years at MPI, Rinaldi conducted research on cellulose depolymerisation in ionic liquids and pioneered the use of ionic liquid solutions in molecular solvents. This innovative work laid the groundwork for advanced calorimetry studies, enabling a deeper understanding of why these ionic liquid solutions outperform parent ionic liquids as solvents for cellulose.

In 2009, Rinaldi advanced to the role of Junior Group Leader at MPI. The following year, his potential was acknowledged by the Alexander von Humboldt Foundation, which bestowed upon him the Sofja Kovalevskaja Award (1.54 M€). This prestigious award provided him with the resources to establish his research group, dedicated to exploring innovative methods for utilising lignin. While at MPI, he also became an external co-principal investigator in the Cluster of Excellence "Tailor-Made Fuels from Biomass" at RWTH Aachen University. He directed research activities with an additional individual budget of 0.9 M€. Among his numerous contributions, he pioneered the 'lignin-first' concept for the fractionation of plant biomass, a breakthrough that has enhanced the valorisation of lignin.

In 2015, Rinaldi moved to London to take up the post of Senior Lecturer in the Department of Chemical Engineering at Imperial College. In 2018, he was promoted to Reader in Applied Chemistry. He currently leads Tomorrow's Chemical Technologies Lab and has been awarded the ERC Consolidator Grant "LIGNINFIRST" (2.0 M€, 2017-2022).

Rinaldi's innovative contributions to developing new methods for processing and using plant biomass were recognised in 2014 with the Willi Keim Prize, awarded by the Advanced Fluids Subject Division of ProcessNet, a joint initiative of DECHEMA and VDI-GVC. Additionally, he has secured industrial funding from Henkel and Susano Fibria, totalling 0.35 M€.

Rinaldi's significant contributions to the field are evident in his over 90 research papers, 14 patent applications in the field of biomass conversion and catalysis, and his supervision of numerous PhD (17), MSc (21) students, and Postdoctoral Research Fellows (20). His scientific work has garnered over 10,500 citations (Google Scholar).

In 2017, Rinaldi's contributions to Chemistry were further acknowledged when he was appointed a Fellow of The Royal Society of Chemistry (FRSC). This esteemed honour is bestowed upon those who have significantly advanced chemical science or demonstrated exceptional professionalism in the field.

He serves as a member of several editorial boards, including ChemCatChem (Advisory Board), Green Chemistry (Advisory Board), Sustainable Chemistry (Advisory Board), Scientific Reports (Editorial Member), npg Materials Sustainability (Associate Editor) and Frontiers in Green Chemistry (Speciality Chief Editor).

Selected Publications

Journal Articles

  • Rinken R, Posthuma D, Rinaldi R, 2022, Lignin stabilization and carbohydrate nature in H-transfer reductive catalytic fractionation: the role of solvent fractionation of lignin oil in structural profiling, Chemsuschem, Vol:16, ISSN:1864-5631, Pages:1-14
  • Kessler M, Rinaldi R, 2022, Kinetic energy dose as a unified metric for comparing ball mills in the mechanocatalytic depolymerization of lignocellulose, Frontiers in Chemistry, Vol:9, ISSN:2296-2646
  • Bartling AW, Stone ML, Hanes RJ, et al., 2021, Techno-economic analysis and life cycle assessment of a biorefinery utilizing reductive catalytic fractionation, Energy & Environmental Science, Vol:14, ISSN:1754-5692, Pages:4147-4168
  • Abu-Omar MM, Barta K, Beckham GT, et al., 2020, Guidelines for performing lignin-first biorefining, Energy & Environmental Science, Vol:14, ISSN:1754-5692, Pages:262-292
  • Kaufman Rechulski MD, Käldström M, Richter U, et al., 2015, Mechanocatalytic depolymerization of lignocellulose performed on hectogram-and kilogram-scales, Industrial & Engineering Chemistry Research, ISSN:0888-5885
  • Ferrini P, Rinaldi R, 2014, Catalytic biorefining of plant biomass to non-pyrolytic lignin bio-oil and carbohydrates through hydrogen transfer reactions, Angewandte Chemie - International Edition, Vol:53, ISSN:1433-7851, Pages:8634-8639
  • Schüth F, Rinaldi R, Meine N, et al., 2014, Mechanocatalytic depolymerization of cellulose and raw biomass and downstream processing of the products, Catalysis Today, Vol:234, Pages:24-30
  • Wang X, Rinaldi R, 2013, A route for lignin and bio-oil conversion: Dehydroxylation of phenols into arenes by catalytic tandem reactions, Angewandte Chemie - International Edition, Vol:52, Pages:11499-11503
  • Rinaldi R, 2014, Catalytic Hydrogenation for Biomass Valorization, Royal Society of Chemistry, ISBN:9781849738019
  • Rinaldi R, 2014, Solvents and Solvent Effects in Biomass Conversion, Catalytic Hydrogenation for Biomass Valorization, Editor(s): Rinaldi, Royal Society of Chemistry, ISBN:9781849738019

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